| Peer-Reviewed

Carbon Nanotube Reinforced Natural Fibers for Biodegradable Nanocomposites

Received: 17 November 2021    Accepted: 6 December 2021    Published: 24 December 2021
Views:       Downloads:
Abstract

Natural fiber-reinforced nanocomposites (NFRCs) are proved as the best alternative for synthetic composites in view of cost and environmental effects. NFRCs have been produced from agro-waste such as banana tree fiber (BFs), because BF are strong, light-weight, and have smaller elongation. To improve the quality of BF, multiwall carbon nanotubes (MWCNTs) are used as reinforcing filler. MWCNTs are functionalized by an ecofriendly radio frequency oxygen plasma processing method. Cellulose nano-crystals (CNC) are extracted from BFs by double hydrolysis process and a simple dip-drying technique has been used to produce NFRCs. Field emission scanning electron micrographs and transmission electron microscopy conform the well functionalization of MWCNTs and also ensure homogeneous incorporation in the BF matrix. The composites continue thermally stable corresponding to BFs. Mechanical strength of the NFRCs are improved owing to the incorporation of MWCNTs. Functional groups in the BFs, CNC and NFRCs are investigated by Fourier transform infrared spectroscopy. The current density of the sample is increased 1000 times than the raw fibers and conductivity increases up to 17 Sm-1, which increases with temperature under the applied voltage 100 V and shows the linier characterization. Therefore, these light-weight biodegradable NFRCs encourage its ability as cost effective industrial conductive composite as usable in electronic devices.

Published in American Journal of Polymer Science and Technology (Volume 7, Issue 4)
DOI 10.11648/j.ajpst.20210704.14
Page(s) 73-79
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Natural Fiber-reinforced Nanocomposites, Banana Fiber, Multiwall Carbon Nanotubes, Cellulose Nano-crystals

References
[1] Barbuta M, Bucur RD, Cimpeanu SM, Paraschiv G, Bucur D (2015). Wastes in Building Materials Industry. Journal of Agroecology 10.5772/58736 (Chapter 3). doi: 10.5772/59933.
[2] Thompson RC, Moore CJ, vom Saal FS, Swan SH (2009). Plastics, the environment and human health: current consensus and future trends. Journal of Philosophical Transactions of the Royal Society B: Biological Sciences, 364 (1526), 2153–2166. doi: 10.1098/rstb.2009.0053.
[3] Thushari GGN, Senevirathna JDM (2020). Plastic pollution in the marine environment. Journal of Heliyon, 6 (8), e04709. doi: 10.1016/j.heliyon.2020.e04709.
[4] Girijappa YGT, Rangappa, SM, Parameswaranpillai J, Siengchin S (2019). Natural Fibers as Sustainable and Renewable Resource for Development of Eco-Friendly Composites: A Comprehensive Review. Journal of Frontiers in Materials, 6, 226–. doi: 10.3389/fmats.2019.00226.
[5] Mohammed L, Ansari MNM, Pua G, Jawaid M, Islam MS (2015). A Review on Natural Fiber Reinforced Polymer Composite and Its Applications. International Journal of Polymer Science, 2015, 1–15. doi: 10.1155/2015/243947.
[6] Mudassar A, Han-Yong J (2020). Generation, Development and Modifications of Natural Fibers. Journal of Natural Fibers: Applications, 10.5772/intechopen. 78111 (Chapter 2). doi: 10.5772/intechopen.86884.
[7] Rajak DK, Pagar DD, Menezes PL, Linul E (2019). Fiber-Reinforced Polymer Composites: Manufacturing, Properties, and Applications. Journal of polymers, 11 (10), 1667. doi.org/10.3390/polym11101667.
[8] Song JH, Murphy RJ, Narayan R, Davies GBH, (2009). Biodegradable and compostable alternatives to conventional plastics. Journal of Philosophical Transactions of the Royal Society B: Biological Sciences, 364 (1526), 2127–2139. doi: 10.1098/rstb.2008.0289.
[9] Sivasankaran, Subbarayan (2019). Polymer Nanocomposites with Different Types of Nanofiller. Journal of Nanocomposites - Recent Evolutions, 10.5772/intechopen.73364 (Chapter 6). doi: 10.5772/intechopen.81329.
[10] Ortega Z, Morón M, Monzón MD, Badalló P, Paz R (2016). Production of Banana Fiber Yarns for Technical Textile Reinforced Composites. Journal of Materials, 9 (5), 370–. doi: 10.3390/ma9050370.
[11] Yang J, Yoo D, Kim Y, Yoon Y (2017). Mechanical Properties of Steam Cured High-Strength Steel Fiber-Reinforced Concrete with High-Volume Blast Furnace Slag. International Journal of Concrete Structures and Materials, 11 (2), 391–401. doi: 10.1007/s40069-017-0200-0.
[12] Lee HV, Hamid SBA, Zain SK (2014). Conversion of Lignocellulosic Biomass to Nanocellulose: Structure and Chemical Process. The Scientific World Journal, 2014, 1–20. doi: 10.1155/2014/631013.
[13] Poletto M, Luiz OH (2015). Crystalline Nanocellulose — Preparation, Modification, and Properties. Journal of Cellulose - Fundamental Aspects and Current Trends, 10.5772/59889 (Chapter 7), –. doi: 10.5772/61899.
[14] Trache D, Tarchoun AF, Derradji M, Hamidon TS, Masruchin N, Brosse N, Hussin MH (2020). Nanocellulose: From Fundamentals to Advanced Applications. Journal of Frontiers in Chemistry, 8, 392–. doi: 10.3389/fchem.2020.00392.
[15] Bhattacharya M (2016). Polymer Nanocomposites—A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers. Journal of Materials, 9 (4), 262. doi: 10.3390/ma9040262.
[16] Chu K, Guo H, Jia C, Yin F, Zhang X, Liang X, Chen H (2010). Thermal Properties of Carbon Nanotube–Copper Composites for Thermal Management Applications. Journal of Nanoscale Research Letters, 5 (5), 868–874. doi: 10.1007/s11671-010-9577-2.
[17] Han S, Meng Q, Araby S, Liu, T, Demiral M (2019). Mechanical and Electrical Properties of Graphene and Carbon Nanotube Reinforced Epoxy Adhesives: Experimental and Numerical Analysis. Journal of Composites Part A: Applied Science and Manufacturing, S1359835X1930073–9. doi: 10.1016/j.compositesa.2019.02.027.
[18] Rahman MJ, Mieno T (2017). Functionalization of Single-Walled Carbon Nanotubes by Citric Acid/Oxygen Plasma Treatment. Fullerenes, Journal of Nanotubes and Carbon Nanostructures, 00–00. doi: 10.1080/1536383X.2017.1347639.
[19] Rahman MJ, Mieno T (2014). Water-Dispersible Multiwalled Carbon Nanotubes Obtained from Citric-Acid-Assisted Oxygen Plasma Functionalization. Journal of Nanomaterials, 2014, 1–9. doi: 10.1155/2014/508192.
[20] Sekar V, Narayana S (2020) CARBON NANOTUBES: A RELIABLE ADDITIVE FOR THE NATURAL FIBER-REINFORCED COMPOSITES. Journal of Engineering Science and Technology 15 (3): 1934-1951.
[21] Mauricio, Jose (2010). Carbon Nanotube Supercapacitors. Journal of Carbon Nanotubes, 10.5772/3451 (Chapter 29), –. doi: 10.5772/39444.
[22] Riaz A, Sarker MR, Saad MHM, Mohamed R (2021). Review on Comparison of Different Energy Storage Technologies Used in Micro-Energy Harvesting, WSNs, Low-Cost Microelectronic Devices: Challenges and Recommendations. Journal of Sensors, 21 (15), 5041. doi.org/10.3390/s21155041.
[23] Ramachandran R, Chen S, Kumer GG (2015). An Overview of Electrochemical Energy Storage Devices of Various Electrodes and Morphological Studies of Supercapacitors. International Journal of ELECTROCHEMICAL SCIENCE, V-10, 10355-10388.
[24] Fiore V, Di Bella G, Valenza A (2015). The effect of alkaline treatment on mechanical properties of kenaf fibers and their epoxy composites. Composites Part B: Engineering, 68, 14–21. doi.org/10.1016/j.compositesb.2014.08.025.
[25] Burmeister CF, Kwade A (2013). Process engineering with planetary ball mills. Journal of Chemical Society Reviews, 42 (18), 7660–. doi: 10.1039/c3cs35455e.
[26] Shaikh HM, Anis A, Poulose AM, Al-Zahrani SM, Madhar NA, Alhamidi A, Alam MA (2021). Isolation and Characterization of Alpha and Nanocrystalline Cellulose from Date Palm (Phoenix dactylifera L.) Trunk Mesh. Journal of Polymers, 13, 1893. doi.org/ 10.3390/polym13111893.
[27] Mahjoub R, Yatim JM, Sam ARM, Hashemi SH (2014). Tensile properties of kenaf fiber due to various conditions of chemical fiber surface modifications. Journal of Construction and Building Materials, 55, 103–113. doi: 10.1016/j.conbuildmat.2014.01.036.
[28] Amin KNM, Annamalai PK, Morrow IC, Martin D, (2015). Production of cellulose nanocrystals via a scalable mechanical method. Journal of RSC Advances, 5 (70), 57133–57140. doi: 10.1039/c5ra06862b.
[29] Islam MJ, Rahman MJ, Mieno T, (2020). Safely functionalized carbon nanotube–coated jute fibers for advanced technology. Journal of Advanced Composites and Hybrid Materials, 3, 285-293. doi: 10.1007/s42114-020-00160-6.
[30] Liu Z, Peng W, Zare Y, Hui D, Rhee KY (2018). Predicting the electrical conductivity in polymer carbon nanotube nanocomposites based on the volume fractions and resistances of the nanoparticle, interphase, and tunneling regions in conductive networks. Journal of RSC Advances, 8 (34), 19001 19010. doi: 10.1039/c8ra00811f.
[31] Rout SK, Tripathy BC, Padhi P, Kar BR, Mishra KG (2017). A green approach to produce silver nano particles coated agro waste fibers for special applications. Surfaces and Interfaces, vol 7, p 87–98. doi: 10.1016/j.surfin.2017.03.004.
[32] Cao X, Ding B, Yu J, Al-Deyab SS (2012) Cellulose nanowhiskers extracted from TEMPO-oxidized jute fibers. Journal of Carbohydrate Polymers 90 (2): 1075–1080. doi: 10.1016/j.carbpol.2012.06.046.
[33] Jandas PJ, Mohanty S, Nayak SK, Srivastava H, Effect of surface treatments of banana fbers on mechanical, thermai, and biodegrability properties of PLA/banana fbers biocomposites. Journal of Polymer Composites, 32 (11), 1689–1700 (2011). doi.org/10.1002/pc.21165.
[34] Shah H, Srinivasulu B, Shit SC (2013). Influence of banana fibre chemical modification on the mechanical and morphological properties of woven banana fabric/unsaturated polyester resin composites. Journal of Polymers Renewable Resources, 4 (2), 61–84. doi.org/10.1177/204124791300400202.
[35] Kenned JJ, Sankaranarayanasamy K, Binoj JS, Chelliah, SK (2020). Thermo-mechanical and morphological characterization of needle punched non-woven banana fbers reinforced polymer composites. Journal of Composites Science and Technology, 185, 107890. doi.org/10.1016/j.compscitech.2019.107890.
[36] Bai L, Bossa N, Qu F, Winglee J, Li G, Sun K, Liang H, Wiesner MR (2016). Comparison of hydrophilicity and mechanical properties of nanocomposite membranes with cellulose nanocrystals (CNCs) and carbon nanotubes (CNTs). Environmental Science & Technology, acs.est.6b04280. doi: 10.1021/acs.est.6b04280.
[37] Lee T, Jeong YG (2015) Regenerated cellulose/multiwalled carbon nanotube composite films with efficient electric heating performance. Journal of Carbohydrate Polymers 133: 456–463. doi: 10.1016/j.carbpol.2015.06.053.
Cite This Article
  • APA Style

    Md. Johurul Islam, Kamaruzzaman, Mohammad Jellur Rahman, M. M. Alam. (2021). Carbon Nanotube Reinforced Natural Fibers for Biodegradable Nanocomposites. American Journal of Polymer Science and Technology, 7(4), 73-79. https://doi.org/10.11648/j.ajpst.20210704.14

    Copy | Download

    ACS Style

    Md. Johurul Islam; Kamaruzzaman; Mohammad Jellur Rahman; M. M. Alam. Carbon Nanotube Reinforced Natural Fibers for Biodegradable Nanocomposites. Am. J. Polym. Sci. Technol. 2021, 7(4), 73-79. doi: 10.11648/j.ajpst.20210704.14

    Copy | Download

    AMA Style

    Md. Johurul Islam, Kamaruzzaman, Mohammad Jellur Rahman, M. M. Alam. Carbon Nanotube Reinforced Natural Fibers for Biodegradable Nanocomposites. Am J Polym Sci Technol. 2021;7(4):73-79. doi: 10.11648/j.ajpst.20210704.14

    Copy | Download

  • @article{10.11648/j.ajpst.20210704.14,
      author = {Md. Johurul Islam and Kamaruzzaman and Mohammad Jellur Rahman and M. M. Alam},
      title = {Carbon Nanotube Reinforced Natural Fibers for Biodegradable Nanocomposites},
      journal = {American Journal of Polymer Science and Technology},
      volume = {7},
      number = {4},
      pages = {73-79},
      doi = {10.11648/j.ajpst.20210704.14},
      url = {https://doi.org/10.11648/j.ajpst.20210704.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20210704.14},
      abstract = {Natural fiber-reinforced nanocomposites (NFRCs) are proved as the best alternative for synthetic composites in view of cost and environmental effects. NFRCs have been produced from agro-waste such as banana tree fiber (BFs), because BF are strong, light-weight, and have smaller elongation. To improve the quality of BF, multiwall carbon nanotubes (MWCNTs) are used as reinforcing filler. MWCNTs are functionalized by an ecofriendly radio frequency oxygen plasma processing method. Cellulose nano-crystals (CNC) are extracted from BFs by double hydrolysis process and a simple dip-drying technique has been used to produce NFRCs. Field emission scanning electron micrographs and transmission electron microscopy conform the well functionalization of MWCNTs and also ensure homogeneous incorporation in the BF matrix. The composites continue thermally stable corresponding to BFs. Mechanical strength of the NFRCs are improved owing to the incorporation of MWCNTs. Functional groups in the BFs, CNC and NFRCs are investigated by Fourier transform infrared spectroscopy. The current density of the sample is increased 1000 times than the raw fibers and conductivity increases up to 17 Sm-1, which increases with temperature under the applied voltage 100 V and shows the linier characterization. Therefore, these light-weight biodegradable NFRCs encourage its ability as cost effective industrial conductive composite as usable in electronic devices.},
     year = {2021}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Carbon Nanotube Reinforced Natural Fibers for Biodegradable Nanocomposites
    AU  - Md. Johurul Islam
    AU  - Kamaruzzaman
    AU  - Mohammad Jellur Rahman
    AU  - M. M. Alam
    Y1  - 2021/12/24
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajpst.20210704.14
    DO  - 10.11648/j.ajpst.20210704.14
    T2  - American Journal of Polymer Science and Technology
    JF  - American Journal of Polymer Science and Technology
    JO  - American Journal of Polymer Science and Technology
    SP  - 73
    EP  - 79
    PB  - Science Publishing Group
    SN  - 2575-5986
    UR  - https://doi.org/10.11648/j.ajpst.20210704.14
    AB  - Natural fiber-reinforced nanocomposites (NFRCs) are proved as the best alternative for synthetic composites in view of cost and environmental effects. NFRCs have been produced from agro-waste such as banana tree fiber (BFs), because BF are strong, light-weight, and have smaller elongation. To improve the quality of BF, multiwall carbon nanotubes (MWCNTs) are used as reinforcing filler. MWCNTs are functionalized by an ecofriendly radio frequency oxygen plasma processing method. Cellulose nano-crystals (CNC) are extracted from BFs by double hydrolysis process and a simple dip-drying technique has been used to produce NFRCs. Field emission scanning electron micrographs and transmission electron microscopy conform the well functionalization of MWCNTs and also ensure homogeneous incorporation in the BF matrix. The composites continue thermally stable corresponding to BFs. Mechanical strength of the NFRCs are improved owing to the incorporation of MWCNTs. Functional groups in the BFs, CNC and NFRCs are investigated by Fourier transform infrared spectroscopy. The current density of the sample is increased 1000 times than the raw fibers and conductivity increases up to 17 Sm-1, which increases with temperature under the applied voltage 100 V and shows the linier characterization. Therefore, these light-weight biodegradable NFRCs encourage its ability as cost effective industrial conductive composite as usable in electronic devices.
    VL  - 7
    IS  - 4
    ER  - 

    Copy | Download

Author Information
  • Department of Physics, Bangladesh University of Engineering and Technology (BUET), Dhaka, Bangladesh

  • Department of Electrical and Electronic Engineering, Noakhali Science and Technology University, Noakhali, Bangladesh

  • Department of Physics, Bangladesh University of Engineering and Technology (BUET), Dhaka, Bangladesh

  • Department of Electrical and Electronic Engineering, Islamic University, Kushtia, Bangladesh

  • Sections